Polymer Science: A Comprehensive Reference, 10 Volume Set by Martin Moeller, Krzysztof Matyjaszewski

By Martin Moeller, Krzysztof Matyjaszewski

The development in polymer technology is printed in basically all chapters of Polymer technology: A complete Reference. In quantity 1, edited by means of Khokhlov and Kremer, this is often mirrored within the enhanced knowing of the houses of polymers in answer, in bulk and in limited events comparable to in skinny movies. quantity 2, edited by means of Spiess, Hashimoto and Takenaka, addresses new characterization innovations, comparable to excessive solution optical microscopy, scanning probe microscopy and different techniques for floor and interface characterization. quantity three, edited via Coates and Sawamoto, provides the nice development accomplished in particular artificial polymerization strategies for vinyl monomers to manage macromolecular structure: the advance of metallocene and post-metallocene catalysis for olefin polymerization, new ionic polymerization strategies, and atom move radical polymerization, nitroxide mediated polymerization, and reversible addition-fragmentation chain move structures because the mostly used controlled/living radical polymerization tools. quantity four, edited via Penczek and Grubbs, is dedicated to kinetics, mechanisms and purposes of ring starting polymerization of heterocyclic monomers and cycloolefins (ROMP), in addition to to numerous much less universal polymerization innovations. Polycondensation and non-chain polymerizations, together with dendrimer synthesis and diverse "click" approaches, are coated in quantity five, edited via Schmidt and Ueda. quantity 6, edited via Mueller and Wooley, specializes in a number of facets of managed macromolecular architectures and gentle nano-objects together with hybrids and bioconjugates. some of the achievements may haven't been attainable with out new characterization suggestions like AFM that allowed direct imaging of unmarried molecules and nano-objects with a precision on hand just recently. a wholly new point in polymer technology is predicated at the mix of bottom-up equipment resembling polymer synthesis and molecularly programmed self-assembly with top-down structuring reminiscent of lithography and floor templating, as awarded in quantity 7, edited by means of Kumacheva and Russell. It encompasses polymer and nanoparticle meeting in bulk and less than restricted stipulations or prompted via an exterior box, together with skinny movies, inorganic-organic hybrids, or nanofibers. quantity eight, edited by means of Muellen and Ober, expands those recommendations targeting functions in complex applied sciences, e.g. in digital and facilities on mixture with most sensible down technique and sensible homes like conductivity. one other kind of performance that's of quickly expanding value in polymer technological know-how is brought in quantity nine, edited by way of Langer and Tirrell. It offers with quite a few features of polymers in biology and medication, together with the reaction of residing cells and tissue to the touch with biofunctional debris and surfaces. The final quantity 10, edited by means of Hoefer, Hickner and McGrath, is dedicated to the scope and strength supplied by way of environmentally benign and eco-friendly polymers, in addition to energy-related polymers. They speak about new applied sciences wanted for a sustainable economic climate in our international of constrained assets. universal to all techniques in Polymer technological know-how: A complete Reference is gaining knowledge of an expanding complexity of the polymer fabrics constitution wanted for a metamorphosis in concentration from commodities to fabrics for varied complicated functions, with regards to strength, atmosphere, and biomedicine.

  • Provides huge and in-depth assurance of all elements of polymer technological know-how from synthesis/polymerization, houses, and characterization equipment and strategies to nanostructures, sustainability and effort, and biomedical makes use of of polymers
  • Provides a definitive resource for these getting into or discovering during this sector by way of integrating the multidisciplinary features of the technological know-how into one distinctive, updated reference work
  • Electronic model has entire cross-referencing and multi-media components
  • Volume editors are global specialists of their box (including a Nobel Prize winner)
  • 269 chapters overlaying all features of polymer technology from synthesis, characterization, homes and nanostructures to biomedical makes use of, sustainability and effort functions

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14 Topology | Synthesis and Properties of Macrocyclic Polymers Scheme 8 Table 2 End functional groups of α,ω-heterodifunctional polymers and activation process for the preparation of cyclic polymers Head group Activation End group Polymer References Vinyl ether Acetal HI/SnCl4 TMSI/TiCl4 Styrenyl Styrenyl Poly(chloroethylvinyl ether) Polystyrene Poly(styrene-b-chloroethylvinyl ether) Poly(styrene-b-ethylene oxide) Polystyrene Poly(methyl methacrylate) Polystyrene Poly(styrene-b-isoprene) Poly(styrene-b-isoprene-b-methyl methacrylate) Polystyrene Poly(styrene-b-methyl methacrylate) Poly(ε-caprolactone) Poly(2-(2-methoxyethoxy)ethyl methacrylate)-b-poly(oligo(ethylene glycol) methyl ether methacrylate) 80 75–77 79 83 84, 85 86 81 82 87 Carboxyl Acetal Amino HCl/MeOH Carboxyl Amino Alkyne Bis(hydroxyl methyl) CuBr Azido Cyclic poly(methyl methacrylate) was prepared from α-carboxy,ω-amino heterodifunctional precursor obtained by a living anionic polymerization of methyl methacrylate using N,N′-diphenylethylenediamine monolithium amide and suc­ cinic anhydride as an initiator and terminator, respectively.

Unruh, D. ; Fréchet, J. M. ; Grubbs, R. H. 38 Copyright 2010 from American Chemical Society. 42 The latter undergoes homolytical cleavage to form on the one side a stable sulfur radical and on the other side a benzyl radical, which is able to react with MA molecules before recombining reversibly with the sulfur radical. With the same method and using cyclic poly(methyl acrylate) (PMA) as macroinitiator instead of cyclic initiator, amphiphilic cyclic block copolymers poly (N-isopropylacrylamide-b-methylacrylate-b-N-isopropylacryla­ mide)s were obtained.

6 Topology | Synthesis and Properties of Macrocyclic Polymers monomer, M, initially added to generate the polymer and characterized by its own propagation and depropagation rate constants, kpM and kdpM. Rings are produced by intramolecular attack of the active chain end X* at one of the functions f of the polymer backbone, which corresponds to a backbiting (bb) reaction. Each of these elementary reactions is characterized by a specific rate constant kbb1 to kbbx, with kbbM = kdpM when the cyclic product formed is identical to the monomer.

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