Organometallic chemistry : a review of literature published by E. Abel, et al.,

By E. Abel, et al.,

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K. Bhareava, Chem. , 1990, 543. G. C. J. H. P. Fackler, Inorn. , 1990, 29, 4408. S. P. F. , 1990, 9, 1973. H. L. H. Dimock. Am. Chem. , 1990. 112, 5869. V. G. V. A. N. G. Perevalova, Metalloorg. , 1989, 2, 1098. G. G. Bolesov, Yu. T. S. G. Kuz'mina, Yu. L. I. Grandberg, Metalloorn. 1989, 2, 560. C. Payne. R. Ramachandran, I. Treurnicht. J. Puddephat, Orpanometallics, 1990, 9. 880; (b) X. Jin, G. Zhou, N. Wu, Y. Tang and H. Huang, Huaxue Xeubao, 1990, 48, 232 (Chem. , 1990, 113, 88547). M. J. L.

Investigations into the effects of introducing groups into the 2-position of apopinene on the ability of B-(iso-2-substitutedapopinocampheyl)-9-BBNderivatives to show enhanced selectivity have been carried out. The 2-ethyl and 2-n-propyl compounds reduce prochiral a$alkynyl ketones and a-keto esters with significantly higher optical induction than AlpineB ~ r a n and e ~ ~a new chiral borohydride containing the iso-2-ethylapopinocampheylgroup is an improved reagent for asymmetric reduction of unhindered aliphatic ketones.

I. B. Ya. Timofeev, Zh. Obschch. Khim,, 1990, 119. 125 P. Paetzold, B. Redenz-Stormannsand R. Boese, Aneew. Chem. Int. Ed. En& 1990. B,900. 126 P. Paetzold, B. Redenz-Stormanns,R. Boese, M. Buhl and P. Von R. Schleyer, ,1990,B. 1059. 127 G. Schmid, M. Polk and R. Boese, Chem,,1990, B, 4421. R. C. Pestana, M. P. Power, Phosphoru&lphur. Silicon Relat. Elem,, 1990, m, 87. 129 R. Seidel and R. Chem. Ber, 1990, 2109. 130 R. Koester, G. Seidel, R. Bcese and B. Wrackmeyer,Chem. , 1990, Ul, 1013. 131 R.

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