On the Road Through Preschool: The Most Complete Book of by Sherrill B. Flora

By Sherrill B. Flora

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Tanomura, T. Nishida, T. Kawaguchi, K . Nakao, H . Nomori, T. Takagi, and K . Itoi, Ger. Offen. 2 138 833. -Interest in the biogenetic relationships of this group continues because of their use as models for squalene biogenesis (Vol. 2, p. 13). "' One of the problems associated with the chrysanthemyl model for squalene biogenesis was that reactions of chrysanthemyl derivatives in solution lead principally to ring-cleavage products. Now Coates and Robinson"' and the Utah group'09 lo' B. A . McAndrew and G .

1972,684. M . Matsui and K . Ueda, Ger. Offen. 2 013 222 (Chem. , 1971,75, I18 029). M. Matsui and F. Horiuchi, Agric. and Biof. Chem. (Japan), 1971, 35, 1984. T . Sugiyama, A. Kobayashi, and K . Yamashita, Agric. and Biol. Chem. (Japan), 1972, 36, 565. 24 Terpenoids und Steroids (79) R = CH20Ac or COMe 1 ( + )-trans-chrysanthemic acid chrysanthemic acid [ e g . pyrethrin I (82) and allethrin (82)]have shown that both in rats' 2o and in houseflies"' one route involves oxidation at the terminal carbon atom of the isopropylidenegroup.

And Biol. Chem. (Japan), 1971,35, 1961. M . J . Bullivant and G . vrethrum Post, 1971, 11, 7 2 ; see also Vol. 1 , p. 14, Vol. 2, p. 15 of these Reports. R . P. Miskus and T. L. Andrews, J . Agric. , 1972, 20, 313. J . H. Tumlinson, R . C. Gueldner, D. D. Hardee, A. C. Thompson, P. A. Hedin, and J . P. Minyard, J . Or g . , 1971, 36, 2616. lZ0 12' I*' 25 Monoterpenoids tween isoprene and but- 1-en-3-one (Scheme 4), followed by conventional reactions with the isomer mixture, and separation at the end.

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