By David L. Bish, Doug Ming
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Extra resources for Natural zeolites: occurrence, properties, applications (Reviews in mineralogy and geochemistry 45)
Ståhl and Artioli (1993) discussed the possibility of a locally ordered H2O superstructure leading to lowering of symmetry. The simplest model would lead to doubling of the a-axis with space group P2. Armbruster and Kohler (1992) and Ståhl et al. (1996) investigated the dehydration of laumontite. The complicated clustering of H2O and accompanying phase transitions in laumontite with varying degrees of hydration were studied by Gabuda and Kozlova (1995) using NMR 1 H and 27Al spectroscopy between 200 and 390 K.
The assignment of goosecreekite to this group is rather arbitrary, as it has a 6-2 SBU (Meier et al. 1996). However, the structure can also be constructed from corner- and edge-sharing fourmembered rings. 8 Å) confine 20 Armbruster & Gunter Figure 7. (a) Framework of yugawaralite (YUG) projected approximately along the a-axis. SiO4 tetrahedra have black edges, and AlO4 tetrahedra have light edges. (b) Framework of goosecreekite (GOO) projected approximately along the a-axis. SiO4 tetrahedra have black edges, and AlO4 tetrahedra have light edges.
A chabazite-offretite epitaxial overgrowth was found by Passaglia and Tagliavini (1994). 60 Å, Z = 1 (Bergerhoff et al. 1958, Baur 1964). Faujasite is actually a rare zeolite, but it is well known, because it has the same framework topology (FAU) as Linde X and Linde Y, synthetic counterparts used as sorbants and catalysts. A review of structural work on synthetic counterparts (Linde X and Linde Y), on ion-exchanged faujasite, and on ion-exchanged and dehydrated faujasite was provided by Smith (1988).