Introduction to Physical Polymer Science HC,2005 by L.H. Sperling

By L.H. Sperling

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13. 14. 15. 16. 17. 18. 19. 20. L. Mandelkern and G. M. Stack, Macromolecules, 17, 87 (1984). P. J. Flory, Principles of Polymer Chemistry, Cornell University, Ithaca, NY, 1953. R. P. Wool, Polymer Interfaces: Structure and Stength, Hanser, Munich, 1995. L. E. Nielsen and R. F. Landel, Mechanical Properties of Polymers, Reinhold, New York, 1994. H. Pasch and B. Trathnigg, HPLC of Polymers, Springer, Berlin, 1997. T. C. Ward, J. Chem. , 58, 867 (1981). L. H. , J. Chem. , 62, 780, 1030 (1985). M.

4 Termination In the termination reaction, two free radicals react with each other. Termination is either by combination, H 2R CH2 O H C. 11) C O C O C2H5 O C2H5 where R now represents a long-chain portion, or by disproportionation, where a hydrogen is transferred from one chain to the other. This latter result 12 CHAIN STRUCTURE AND CONFIGURATION produces in two final chains. 10), this termination step is normally head-to-head. As a homopolymer, poly(ethyl acrylate) is widely used as an elastomer or adhesive, being a polymer with a low Tg, -22°C.

13. 14. 15. 16. 17. 18. 19. 20. L. Mandelkern and G. M. Stack, Macromolecules, 17, 87 (1984). P. J. Flory, Principles of Polymer Chemistry, Cornell University, Ithaca, NY, 1953. R. P. Wool, Polymer Interfaces: Structure and Stength, Hanser, Munich, 1995. L. E. Nielsen and R. F. Landel, Mechanical Properties of Polymers, Reinhold, New York, 1994. H. Pasch and B. Trathnigg, HPLC of Polymers, Springer, Berlin, 1997. T. C. Ward, J. Chem. , 58, 867 (1981). L. H. , J. Chem. , 62, 780, 1030 (1985). M.

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