Inorganic Syntheses, Vol. 14 by Wold A., Ruff J.K. (eds.)

By Wold A., Ruff J.K. (eds.)

The volumes during this carrying on with sequence supply a compilation of present ideas and concepts in inorganic artificial chemistry. contains inorganic polymer syntheses and education of vital inorganic solids, syntheses utilized in the improvement of pharmacologically energetic inorganic compounds, small-molecule coordination complexes, and comparable compounds. additionally includes precious info on transition organometallic compounds together with species with metal-metal cluster molecules. All syntheses awarded right here were proven.

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The state is written as 3FeII'FeIII or more accurately Fe 2 • 25 as a formaZ charge. By contrast, the two-iron sulfur protein centers have so-called trapped iron(II) and iron(III) valencies in [Fe2S2(SR)4]- which are not in resonance (11). The sites are structurally different and any valency interchange between the two iron sites, if it in fact occurs, would be a chemical reaction and involve a structural change. The delocalization in the four-iron clusters means that individual oxidation states of iron are not very useful.

C. : 1979, J. Am. Chem. , 101, pp. 6562-6570. S. : 1979, Adv. Inorg. , 1, pp. 235-252. , Rutter, R. , 103, pp. 102-105. , Foner, S. : 1976, Inorg. , 15, pp. 1095-1100. SECTION B I RON METABOLI SM FERRITIN - THE STRUCTURE AND FUNCTION OF AN IRON STORAGE PROTEIN Robert R. Crichton Unite de Biochimie, Universite Catholique de Louvain, B-1348 Louvain-la-Neuve, Belgium. The requirement for an iron storage protein is discussed and the distribution and role of ferritin in iron metabolism are reviewed.

1964, "Porphyrins and Meta11oporphyrins", Elsevier: New York, pp. 67-71. E. : 1979, J. Am. Chem. , 101, pp. 3653-3655. K. R. , Elsevier: New York, in press. G. : 1976, P~oc. Nat. Acad. Sci. , 73, pp. 1078-1082. : 1972, P~oc. Nat. Acad. Sci. , 69, pp. 2263-2267. : 1979, Natu~e, 282, pp. 806-810. : 1978, Natu~e, 275, pp. 73-74. : 1977, "Iron-sulfur Proteins", Academic Press: NeH York, Vol III, pp. 157-204. V. : 1980, Ann. Rev. , 49, pp. 139-161. , Que, L. Jr. : 1974, J. Am. Chem. , 96, pp. 4159-4167.

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