Electrochemistry by Eberhard Steckhan, Mary Anne Fox, Hans-Jürgen Schäfer, K.

By Eberhard Steckhan, Mary Anne Fox, Hans-Jürgen Schäfer, K. Uneyama, James H.P. Utley

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The information from electrochemical voltage spectroscopy (EVS) on thermodynamic parameters 2o4-206) is in essence the same as that obtained by cyclic voltammetry. This technique involves slowly stepwise incrementing the voltage of the electrochemical cell and recording the charge removed from (or injected to) the polymer after each voltage step. Since the cell current in EVS measurements can be kept arbitrarily low, non-equilibrium effects such as IR-losses, over-potentials, and diffusional phenomena are virtually eliminated.

8:51 179. Salmon M, Diaz AF, Logan A J, Krounbi M, Bargon J (1982) Mot. Cryst. Liq. Cryst. 83 : 1297 180. Hotta S, Hosaka T, Shimotsuma W, Synth. Met. (1983) 6:69 181. Chung TC, Kaufman JH, Heeger AJ, Wudl F (1984) Phys Rev. 30B: 702 182. Kaneto K, Yoshino K, Inuishi Y (1983) Jpn. J. Appl. Phys. 22: L 412, L 567 t83a. Shacklette LW, Elsenbaumer RL, Baughman RH (1983) J. Phys. Coll. 44 C3:559 183b. Shacklette LW, Elsenbaumer RL, Chance RR, Sowa JM, Ivory DM, Miller GG, Baughman RH: J. Chem. Soc.

H6rhold H-H, Opfermann J, Atrat P, Tauer K-D, Drefahl G: 5th Internat. Symp. Polykondensation, Varna 1975, in "Polykondensationsprozesse", Sofia 1976, Verlag der Bulg. Akad. , p. 17l 152c. H6rhold H-H, Helbig M, Raabe D, Opfermann J, Scherf U, Stockmann R, WeiB D (1987) Z. Chem. 27:126 153. Genies EM, Pernaut J-M (1985) J. Electroanal. Chem. 191 : 111 154. Brazovskii SA, Kirova N (1981) JEPT Lett. 33:4 155. Br6das JL, Chance RR, Silbey R (1981) Mol. Cryst. Liq. Cryst. 77: 319; (1982) Phys. Rev.

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