Biocatalysis in Oil Refining by M. M. Ramirez-Corredores

By M. M. Ramirez-Corredores

Biocatalysis in Oil Refining specializes in petroleum refining bioprocesses, developing a connection among technological know-how and technology.The micro organisms and biomolecules tested for biocatalytic reasons for oil refining techniques are completely exact. Terminology utilized by biologists, chemists and engineers is introduced right into a universal language, supporting the certainty of complicated biological-chemical-engineering matters. difficulties to be addressed through the long run R&D actions and by way of new applied sciences are defined and summarized within the final bankruptcy.

Show description

Read Online or Download Biocatalysis in Oil Refining PDF

Best chemistry books

Opioid Analgesics: Chemistry and Receptors

The quickly burgeoning learn of the previous 20 years on agonist-antagonist analgesics and opioid receptors makes this exhaustive evaluation of opioid anal­ gesics relatively appropriate and well timed. After an introductory bankruptcy the extra 12 chapters start logically with morphine and congeners (4- epoxymorphinans) and finish with opioid receptors.

Additional info for Biocatalysis in Oil Refining

Example text

Aromatics, olefins and in general, unsaturated compounds undergo hydrogenation reactions, usually unwanted due to their detrimental effect on the operating costs, derived from an excessive consumption of hydrogen. Aromatic saturation, however, is used in jet fuel to improve the smoke point and in diesel for cetane enhancement. In the case of gasoline, extreme hydrogenation leads to a deterioration of the fuel performance parameters. Aromatic saturation reactions are reversible and exothermic, and at typical reaction conditions, do not attain 100% conversion.

Laboratory studies indicate that the nature of deposited coke depends on the chemical nature of the coke precursor molecules and on the operating conditions [33,34]. Therefore, the understanding of coke evolution under industrial conditions is an extremely difficult task. However, the characterization of a spent catalyst has been studied on a sample after four years of industrial operation [35]. The changes in the morphological structure of the layered-stacking of the MoS2 phase [36] and the existence of a metal carbide phase has been confirmed.

For the same reason (lower hydrogenation capacity), CoMo catalysts are the least active for HDN reactions. NiMo catalysts though designed for HDS are highly active for hydrogenation reac­ tions and in consequence for HDN. ). However, their sensitivity to hydrogen pressure results in higher working pressures than CoMo. The HDS activity of NiMo catalysts is especially dependant on their hydrogenation activity, and consequently is more sensitive to N-compounds deactivation. NiW catalysts are the most active for hydrogenation and are best suited for aromatic saturation and hydrocracking.

Download PDF sample

Rated 4.37 of 5 – based on 41 votes