By W.G. Frankenburg, V.I. Komarewsky, E.K. Rideal (Eds.)
With this moment quantity of Advances in Catalysis, the editors have persevered their efforts to give the numerous features of the catalytic approach. a couple of hugely certified males have contributed to this quantity. From the theoretical remedies of trouble-free methods among molecules reacting at stable surfaces to the technically vital activities of fluoride catalysts, and to catalytic polymerizations of olefins, the reader turns into conversant in manifold rules and with a few general experimental effects in terms of catalytic phenomena. Our loss of an entire figuring out of catalytic motion, and our corresponding lack of ability to ''predict'' the way of attaining a wanted catalytic response, make it fundamental for everybody operating during this course to familiarize himself with the adventure of others, whether such adventure was once amassed in distant sectors of this huge box.
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Additional resources for Advances in Catalysis, Vol. 2
I P A T I E F F Formation of products of rearrangement may be looked upon as occurring by way of loss of hydrogen from a carbon atom which is not adjacent to the carbon atom holding the phosphate radical. This results in the transitory formation of a cyclopropane or cyclobutane ring which then opens to yield the rearranged olefin.
V. Macropolymerization a t Low Temperature.. . 1. Boron Fluoride. Fluori . 2. Titanium Tetrachlor .................................... 62 71 75 . . . . . . . 76 .......................... 77 References.. 78 References. . . . . . . . . . . . . . . . . . . . . .. .. .. .. . . . . I. INTRODUCTION I . Scope The chemical literature contains 'very many papers on the polymerization of olefins, written both from the theoretical and practical standpoint.
Physik. Chem. , Z. physik. Chem. , Z. physik. Chem. , J . Chem. Phys. 3, 107 (1935). , Trans. , Laidler, K. , Rate Processes in Chemical Reactions. McGraw-Hill, New York, 1941. 2. , 2. Elektrochem. 39, 269 (1939). This Page Intentionally Left Blank The Mechanism of the Polymerization of Alkenes LOUIS SCHMERLING AND V. N. IPATIEFF liniversal Oil Products Company, Riverside, Illinois CONTENTS Page I. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21 1.